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The results of 13C and 2H n.m.r. analyses of [2H33]- and [1,2-13C22]-acetate-enriched tajixanthone are reported, which indicate, inter alia, that ring cleavage of an anthraquinone, and not anthrone, precursor must precede C-prenylation, and that dihydropyran ring formation precedes xanthone ring formation during biosynthesis of tajixanthone.
E. Bardshiri and T. J. Simpson, J. Chem. Soc., Chem. Commun., 1981, 195 DOI: 10.1039/C39810000195
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